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An Alternative Demetalation Method for Cu(I)-Phenanthroline-Based Catenanes and Rotaxanes
[Image: see text] A new and less hazardous procedure for demetalation of Cu(I)-phenanthroline-based interlocked molecules, using aqueous NH(4)OH rather than toxic KCN, has been developed. The conditions are compatible with materials containing nucleophile-sensitive appended groups such as C(60), and...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2011
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3070403/ https://ncbi.nlm.nih.gov/pubmed/21384822 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200304d |
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