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Towards identification of the reaction coordinate directly from the transition state ensemble using the kernel PCA method

We propose a new method for analyzing an ensemble of transition states in order to extract components of the reaction coordinate. We use the kernel Principal Component Analysis (kPCA), which is a generalization of the ordinary PCA that does not make a linearization approximation We applied this meth...

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Detalhes bibliográficos
Main Authors: Antoniou, Dimitri, Schwartz, Steven D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3058940/
https://ncbi.nlm.nih.gov/pubmed/21332236
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp111682x
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