Water dynamics in small reverse micelles in two solvents: Two-dimensional infrared vibrational echoes with two-dimensional background subtraction

Water dynamics as reflected by the spectral diffusion of the water hydroxyl stretch were measured in w(0) = 2 (1.7 nm diameter) Aerosol-OT (AOT)∕water reverse micelles in carbon tetrachloride and in isooctane solvents using ultrafast 2D IR vibrational echo spectroscopy. Orientational relaxation and...

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Main Authors: Fenn, Emily E., Wong, Daryl B., Fayer, M. D.
Format: Artigo
Jezik:Inglês
Izdano: American Institute of Physics 2011
Teme:
Condensed Phase Dynamics, Structure, and Thermodynamics: Spectroscopy, Reactions, and Relaxation
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3055695/
https://ncbi.nlm.nih.gov/pubmed/21303143
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.3532542
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