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Spirodiepoxides: Synthesis of Epoxomicinoids
Three closely related analogs of epoxomicin have been synthesized. Allene-derived spirodiepoxides were key intermediates. Spirodiepoxide formation and stereochemical dependence on solvent, oxidant, and allene structure was cataloged. The facial selectivity of the first epoxidation of 1,3-disubstitut...
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| 主要な著者: | , , , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2009
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3043609/ https://ncbi.nlm.nih.gov/pubmed/19761213 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901320f |
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