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[3+2] Cycloadditions of Aryl Cyclopropyl Ketones by Visible Light Photocatalysis
We report a new method for the formal [3+2] reaction of aryl cyclopropyl ketones with olefins to generate highly substituted cyclopentane ring systems. The key initiation step in this process is the one-electron reduction of the ketone to the corresponding radical anion, which is accomplished using...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3033486/ https://ncbi.nlm.nih.gov/pubmed/21214249 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107849y |
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