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The intriguing modeling of cis–trans selectivity in ruthenium-catalyzed olefin metathesis
In this study we have investigated computationally the origin of the cis–trans selectivity in the Ru-catalyzed cross metathesis (CM) of a prototype monosubstituted olefin, i.e., propene. Our calculations suggest that the origin of the preferential formation of trans-olefins is in the product release...
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| Main Authors: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Beilstein-Institut
2011
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3028549/ https://ncbi.nlm.nih.gov/pubmed/21286393 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.7 |
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