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Hypercrosslinking: New approach to porous polymer monolithic capillary columns with large surface area for the highly efficient separation of small molecules

Monolithic polymers with an unprecedented surface area of over 600 m(2)/g have been prepared from a poly(styrene-co-vinylbenzyl chloride-co-divinylbenzene) precursor monolith that was swollen in 1,2-dichloroethane and hypercrosslinked via Friedel-Crafts reaction catalyzed by ferric chloride. Both th...

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Detalhes bibliográficos
Main Authors: Urban, Jiri, Svec, Frantisek, Fréchet, Jean M.J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3022388/
https://ncbi.nlm.nih.gov/pubmed/21092973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chroma.2010.10.100
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