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Use of the Simple and Extended Grunwald-Winstein Equations in the Correlation of the Rates of Solvolysis of Highly Hindered Tertiary Alkyl Derivatives

The original Grunwald-Winstein equation (1948) involved the development of a scale of solvent ionizing power (Y). Subsequent work has refined this scale and involved the development of scales of solvent nucleophilicity (N) and a term to correct for deviations when aromatic rings are present, governe...

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Bibliografiske detaljer
Main Authors: Kevill, Dennis N., D’Souza, Malcolm J.
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3020085/
https://ncbi.nlm.nih.gov/pubmed/21243118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.2174/138527210791130505
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