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(2SR,3SR)-Isopropyl 3-{[dimeth­yl(phenyl)­sil­yl]meth­yl}-2-hy­droxy-2-vinyl­pent-4-enoate

The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si—C bond distances are in the range 1.858 (2)–1.880 (2) Å and an intra­molecular O—H⋯O hydrogen...

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Detalhes bibliográficos
Main Authors: Nelson, Bjoern, Schürmann, Markus, Preut, Hans, Hiersemann, Martin
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3011670/
https://ncbi.nlm.nih.gov/pubmed/21589408
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536810044818
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