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Synthesis of a Benzodiazepine-derived Rhodium NHC Complex by C-H Bond Activation
The synthesis and characterization of a Rh(I)-NHC complex generated by C-H activation of 1,4-benzodiazepine heterocycle are reported. This complex constitutes a rare example of a carbene tautomer of a 1,4-benzodiazepine aldimine stabilized by transition metal coordination and demonstrates the abilit...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2008
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3010370/ https://ncbi.nlm.nih.gov/pubmed/21191469 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om8000839 |
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