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Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual Activation of an Ene Reaction

A tris-triphenylphosphinegold oxonium tetrafluoroborate, [(Ph(3)PAu)(3)O]BF(4), catalyzes the rearrangement of 1,5-allenynes to produce cross-conjugated trienes. Experimental and computational evidence shows that the ene reaction proceeds through a unique nucleophilic addition of an allene double bo...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Cheong, Paul Ha-Yeon, Morganelli, Philip, Luzung, Michael R., Houk, K. N., Toste, F. Dean
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2008
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2995695/
https://ncbi.nlm.nih.gov/pubmed/18327944
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja711058f
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