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α,β-Aziridinylphosphonates by lithium amide-induced phosphonyl migration from nitrogen to carbon in terminal aziridines
N-Phosphonate terminal aziridines undergo lithium 2,2,6,6-tetramethylpiperidide-induced N- to C-[1,2]-anionic phosphonyl group migration under experimentally straightforward conditions, to provide a stereocontrolled access to synthetically valuable trans-α,β-aziridinylphosphonates. The utility of th...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
Beilstein-Institut
2010
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2981828/ https://ncbi.nlm.nih.gov/pubmed/21085508 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.110 |
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