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Tri-μ-ethanethiolato-bis{[η(5)-1,2,3,4-tetramethyl-5-(trimethylsilyl)cyclopentadienyl]iron(II,III)}(Fe(II)–Fe(III))
The title complex, [Fe(2)(C(2)H(5)S)(3)(C(12)H(21)Si)(2)], has an unusual Fe(2)S(3) core. The two 1,2,3,4-tetramethyl-5-(trimethylsilyl)cyclopentadienyl (Cp′) ligands coordinate to the Fe atoms with their C(5) planes perpendicular [dihedral angles = 88.23 (7) and 88.55 (7)°] to the Fe—Fe vector,...
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
International Union of Crystallography
2009
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| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2972053/ https://ncbi.nlm.nih.gov/pubmed/21578582 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536809045735 |
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