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(9S,13R,14R)-7,8-Didehydro-3,4,7-trimeth­oxy-17-methyl­morphinan-6-one

The title compound, C(20)H(25)NO(4), was synthesized by a Mitsunobu reaction of sinomenine [(9S,13R,14R)-7,8-didehydro-4-hydroxy-3,7-dimethoxy-17-methylmorphinan-6-one] with methanol. The chiral centers were unchanged during the reaction. Intra­molecular C—H⋯O hydrogen bonds result in the formation...

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Detalhes bibliográficos
Main Authors: Li, Yu-Feng, Qian, Yi, Yin, Li-He, Lv, Ran, Zhu, Hong-Jun
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2969083/
https://ncbi.nlm.nih.gov/pubmed/21582431
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536808040749
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