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Effective charge and coil-globule transition of a polyelectrolyte chain

Considering the adsorption of counterions on an isolated polyelectrolyte (PE) chain and using a variational theory, phase boundaries and the critical point for the first-order coil-globule transition are calculated. The transition is induced cooperatively by counterion adsorption and chain conformat...

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Detalhes bibliográficos
Main Authors: Kundagrami, Arindam, Muthukumar, M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2967044/
https://ncbi.nlm.nih.gov/pubmed/21052522
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma9020888
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