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Chiral Photochemistry in a Confined Space: Torquoselective Photoelectrocyclization of Pyridones within an Achiral Hydrophobic Capsule

Chiral induction during the photoelectrocyclization of pyridones included within octa acid (OA) capsule has been established. Chiral induction is brought about by a chiral auxiliary appended to the reactive pyridone moiety. Importantly, the same chiral auxiliary while ineffective in acetonitrile sol...

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Detalhes bibliográficos
Main Authors: Sundaresan, Arun Kumar, Gibb, Corinne L. D., Gibb, Bruce C., Ramamurthy, V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2964841/
https://ncbi.nlm.nih.gov/pubmed/21037975
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.01.110
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