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P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide

The title compound, C(36)H(30)NP(3), a structural isomer of tris­(diphenyl­phosphino)amine, was unexpectedly isolated as the sole phospho­rus-containing product from the reaction of Mg[N(PPh(2))(2)](2)(THF)(2) (THF is tetra­hydro­furan) with CO(2). Its identity was confirmed by (31)P NMR spectroscop...

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Main Authors: Dickie, Diane A., Kemp, Richard A.
格式: Artigo
語言:Inglês
出版: International Union of Crystallography 2008
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2962250/
https://ncbi.nlm.nih.gov/pubmed/21203164
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536808020412
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