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[μ-11,23-Dibromo-3,7,15,19-tetraazatricyclo[19.3.1.1(9,13)]hexacosa-1(25),2,7,9,11,13(26),14,19,21,23-decaene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]

The title complex, [Cu(2)(C(22)H(20)Br(2)N(4)O(2))(ClO(4))(2)], was prepared by the condensation of 2,6-diformyl-4-bromophenol with 1,3-diaminopropane in the presence of copper(II) ions. The macrocyclic ligand shows an approximately planar structure except for the two propene groups in the macrocy...

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Detalhes bibliográficos
Main Authors:	Zhang, Han-Ping, Zhu, Jin-Xia, Zhou, Hong, Pan, Zhi-Quan
Formato:	Artigo
Idioma:	Inglês
Publicado em:	International Union of Crystallography 2008
Assuntos:	Metal-Organic Papers
Acesso em linha:	https://ncbi.nlm.nih.gov/pmc/articles/PMC2960380/ https://ncbi.nlm.nih.gov/pubmed/21201303 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536808000354
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[μ-11,23-Dibromo-3,7,15,19-tetra­aza­tri­cyclo­[19.3.1.1(9,13)]hexa­cosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]

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[μ-11,23-Dibromo-3,7,15,19-tetraazatricyclo[19.3.1.1(9,13)]hexacosa-1(25),2,7,9,11,13(26),14,19,21,23-decaene-25,26-diolato-κ(4) N (3),N (7),O,O′:κ(4) O,O′,N (15),N (19)]bis[perchloratocopper(II)]