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[1,3-Bis(diphenyl­phosphino)propane-κ(2) P,P′]diiodido(perfluoro­propyl)rhodium(III) dichloro­methane solvate

The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typica...

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Detalhes bibliográficos
Main Authors: Panthi, Basu, Gipson, Stephen L., Franken, Andreas
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2959266/
https://ncbi.nlm.nih.gov/pubmed/21201064
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536808029978
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