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UV Resonance Raman Investigation of Electronic Transitions in α-helical and Polyproline II-like Conformations

UV resonance Raman (UVRR) excitation profiles and Raman depolarization ratios were measured for a 21-residue predominantly alanine peptide, AAAAA(AAARA)(3)A (AP), excited between 194 and 218 nm. Excitation within the π→π* electronic transitions of the amide group results in UVRR spectra dominated by...

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Detalhes bibliográficos
Main Authors: Sharma, Bhavya, Bykov, Sergei V., Asher, Sanford A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2958432/
https://ncbi.nlm.nih.gov/pubmed/18712913
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp801110q
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