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Rowlinson’s concept of an effective hard sphere diameter

Attention is drawn to John Rowlinson’s idea that the repulsive portion of the intermolecular interaction may be replaced by a temperature-dependent hard sphere diameter. It is this approximation that made the development of perturbation theory possible for realistic fluids whose intermolecular inter...

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Autor principal: Henderson, Douglas
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2954409/
https://ncbi.nlm.nih.gov/pubmed/20953320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/je9009464
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