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CO and O(2) Binding to Pseudo-Tetradentate Ligand-Copper(I)-Complexes with a Variable N-Donor Moiety: Kinetic/Thermodynamic Investigation Reveals Ligand Induced Changes in Reaction Mechanism
The kinetics, thermodynamics, and coordination dynamics for O(2) and CO 1:1 binding to a series of pseudo-tetradentate ligand-copper(I)-complexes ((D)LCu(I)) to give Cu(I)/O(2) and Cu(I)/CO product species are reported. The (D)LCu(I) series possess an identical tridentate core structure where the cu...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2952189/ https://ncbi.nlm.nih.gov/pubmed/20726586 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104107q |
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