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Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions of Enantiomerically Enriched Potassium β-Trifluoroboratoamides with Various Aryl- and Hetaryl Chlorides

[Image: see text] Enantiomerically enriched potassium β-trifluoroboratoamides were synthesized as air stable solids in greater than 95:5 dr using pseudoephedrine as the chiral auxiliary. With these chiral nucleophiles, Suzuki-Miyaura cross-coupling reactions were carried out with various aryl- and h...

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Bibliographic Details
Main Authors: Molander, Gary A., Shin, Inji, Jean-Gérard, Ludivine
Format: Artigo
Language:Inglês
Published: 2010
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2946850/
https://ncbi.nlm.nih.gov/pubmed/20831191
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101865e
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