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Development of an Enantioselective Route towards the Lycopodium Alkaloids: Total Synthesis of Lycopodine
Synthesis of a C(15)-desmethyl tricycle core of lycopodine has been accomplished. Key steps in the synthetic sequence include organocatalytic, intramolecular Michael addition of a keto sulfone and a tandem 1,3-sulfonyl shift / Mannich cyclization to construct the tricyclic core ring system. Syntheti...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2943527/ https://ncbi.nlm.nih.gov/pubmed/20586477 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100916x |
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