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Synthesis of Conjugated Polymers Containing cis-Phenylenevinylenes by Titanium Mediated Reductions

The utility of Sato's titanium-mediated reduction of alkynes towards the synthesis of all cis-poly(phenylenevinylene)s (PPVs) is demonstrated by the syn-selective reduction of a variety of model diynes as well as a tetrayne. This technique was then applied to the reduction of a poly(phenyleneet...

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Autors principals: Moslin, Ryan M., Espino, Christine G., Swager, Timothy M.
Format: Artigo
Idioma:Inglês
Publicat: 2008
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2934907/
https://ncbi.nlm.nih.gov/pubmed/20827441
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma8022519
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