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Total Synthesis of Pareitropone via Radical Anion Coupling

[Image: see text] A concise (9-step) synthesis of the tropoloisoquinoline alkaloid pareitropone has been achieved starting from 2-bromoisovanillin. The key step features oxidative cyclization of a readily available phenolic nitronate for the convenient construction of the fused tropone ring. This wo...

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Hlavní autoři: Hong, Suk-Koo, Kim, Hyeonjeong, Seo, Youngran, Lee, Sang Hyup, Cha, Jin Kun, Kim, Young Gyu
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2929295/
https://ncbi.nlm.nih.gov/pubmed/20698500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1017849
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