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A general enantioselective route to the chamigrene natural product family

Described in this report is an enantioselective route toward the chamigrene natural product family. The key disconnections in our synthetic approach include sequential enantioselective decarboxylative allylation and ring-closing olefin metathesis to form the all-carbon quaternary stereocenter and sp...

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Detalhes bibliográficos
Main Authors: White, David E., Stewart, Ian C., Seashore-Ludlow, Brinton A., Grubbs, Robert H., Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2925317/
https://ncbi.nlm.nih.gov/pubmed/20798895
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2010.04.128
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