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High lipophilicity of meta Mn(III) N-alkylpyridylporphyrin-based SOD mimics compensates for their lower antioxidant potency and makes them equally effective as ortho analogues in protecting SOD-deficient E. coli

Lipophilicity/bioavailibility of Mn(III)N-alkylpyridylporphyrin-based SOD mimics has major impact on their in vivo ability to suppress oxidative stress. Meta isomers are less potent SOD mimics than ortho analogues, but are 10-fold more lipophilic and more planar. Enhanced lipophilicity contributes t...

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Detalhes bibliográficos
Main Authors: Kos, Ivan, Benov, Ludmil, Spasojević, Ivan, Rebouças, Júlio S., Batinić-Haberle, Ines
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2920616/
https://ncbi.nlm.nih.gov/pubmed/19954250
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jm900576g
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