(S)-3-Dimethyl­amino-2-{(4S,5R)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}-2-hydroxy­propanoic acid

The Kiliani reaction on 1-de­oxy-(N,N-dimethyl­amino)-d-fructose, itself readily available from reaction of dimethyl­amine and d-glucose, proceeded to give access to the title β-sugar amino acid, C(15)H(27)NO(7). X-ray crystallography determined the stereochemistry at the newly formed chiral center....

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Bibliographic Details
Main Authors: Jenkinson, Sarah F., Hotchkiss, David J., Cowley, Andrew R., Fleet, George W. J., Watkin, David J.
Format: Artigo
Language:Inglês
Published: International Union of Crystallography 2007
Subjects:
Organic Papers
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2915345/
https://ncbi.nlm.nih.gov/pubmed/21200859
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536807066676
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