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Low Pressure Vinylation of Aryl and Vinyl Halides via Heck-Mizoroki Reactions Using Ethylene

Aryl bromides and iodides in the presence of catalytic amounts of a palladacycle derived from acetophenone oxime and 2 equivalents of potassium acetate react with ethylene under ambient pressure (15–30 psi) to give the corresponding vinylarenes. The reactions work with both electron-deficient and el...

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Autors principals: Smith, Craig R., RajanBabu, T. V.
Format: Artigo
Idioma:Inglês
Publicat: 2010
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2910319/
https://ncbi.nlm.nih.gov/pubmed/20676383
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.11.017
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