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Nonproductive Events in Ring-Closing Metathesis using Ruthenium Catalysts

[Image: see text] The relative TONs of productive and nonproductive metathesis reactions of diethyl diallylmalonate are compared for eight different ruthenium-based catalysts. Nonproductive cross metathesis is proposed to involve a chain-carrying ruthenium methylidene. A second more-challenging subs...

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Detalhes bibliográficos
Main Authors: Stewart, Ian C., Keitz, Benjamin K., Kuhn, Kevin M., Thomas, Renee M., Grubbs, Robert H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2908527/
https://ncbi.nlm.nih.gov/pubmed/20518557
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1029045
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