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[(H(2)O)(terpy)Mn(μ-O)(2)Mn(terpy)(OH(2))](NO(3))(3) (terpy = 2,2′:6,2″-terpyridine) and its relevance to the oxygen-evolving complex of photosystem II examined through pH dependent cyclic voltametry

Photosynthetic water oxidation occurs naturally at a tetranuclear manganese center in the photosystem II protein complex. Synthetically mimicking this tetramanganese center, known as the oxygen-evolving complex (OEC), has been an ongoing challenge of bioinorganic chemistry. Most past efforts have ce...

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Detalhes bibliográficos
Main Authors: Cady, Clyde W., Shinopoulos, Katherine E., Crabtree, Robert H., Brudvig, Gary W.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2907169/
https://ncbi.nlm.nih.gov/pubmed/20372724
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b922087a
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