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Schiff base chemistry of the {ReO}(3+) core: structural characterization of the unusual ‘3 + 2’ complex [ReO(η(3)-OC(6)H(4)–CH=NC(6)H(4)-2-S)(η(2)-OC(6)H(4) [Image: see text])]
The reaction of [ReOCl(3)(PPh(3))(2)] with salicylaldehyde-2-mercaptoanil (1) in methanol yields [ReO(OCH(3))(PPh(3))(η(3)-OC(6)H(4)CH=NC(6)H(4)S)] (3). Reaction of 3 with 2-(2-hydroxyphenyl)benzothiazole (2) produces [ReO(η(3)-OC(6)H(4)CH=NC(6)H(4)S)( η(2)-OC(6)H(4) [Image: see text])] (4) in good...
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Main Authors: | , , , |
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Format: | Artigo |
Language: | Inglês |
Published: |
2000
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Subjects: | |
Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2898268/ https://ncbi.nlm.nih.gov/pubmed/20617115 |
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