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Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si- or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans

A novel highly efficient regiodivergent Au-catalyzed cycloisomerization of allenyl- and homopropargylic ketones into synthetically valuable 2- and 3-silylfurans has been designed with the aid of the DFT calculations. This cascade transformation features 1,2-Si- or 1,2-H migrations in a common Au-car...

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書誌詳細
主要な著者: Dudnik, Alexander S., Xia, Yuanzhi, Li, Yahong, Gevorgyan, Vladimir
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2896962/
https://ncbi.nlm.nih.gov/pubmed/20476771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910290c
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