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Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si- or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans
A novel highly efficient regiodivergent Au-catalyzed cycloisomerization of allenyl- and homopropargylic ketones into synthetically valuable 2- and 3-silylfurans has been designed with the aid of the DFT calculations. This cascade transformation features 1,2-Si- or 1,2-H migrations in a common Au-car...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2010
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| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2896962/ https://ncbi.nlm.nih.gov/pubmed/20476771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910290c |
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