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Thorpe-Ingold Acceleration of Oxirane Formation is Mostly a Solvent Effect
The Thorpe-Ingold hypothesis for the gem-dimethyl effect in the cyclization reactions of 2-chloroethoxide derivatives has been investigated computationally in the gas phase and in aqueous solution. Ab initio MP2/6-311+G(d,p) and CBS-Q calculations reveal little intrinsic difference in reactivity wit...
में बचाया:
| मुख्य लेखकों: | , |
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| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
2010
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2892976/ https://ncbi.nlm.nih.gov/pubmed/20524660 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1023755 |
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