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Intramolecular [1 + 2] and [3 + 2] Cycloaddition Reactions of Cyclopropenone Ketals

The first intramolecular thermal reactions of cyclopropenone ketals are reported enlisting substrates tethered to an electron-deficient olefin bearing a single electron-withdrawing substituent. Whereas the intermolecular variants of the reactions provide only the products of an endo selective [1 + 2...

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Autors principals: Patel, Paresma R., Boger, Dale L.
Format: Artigo
Idioma:Inglês
Publicat: 2010
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2892887/
https://ncbi.nlm.nih.gov/pubmed/20527885
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103933n
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