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Substituent effects on regioselectivity in the autoxidation of nonconjugated dienes

Free radical oxidation of several 1,4-dienes was carried out in the presence of variable concentrations of α-tocopherol to investigate the effect of diene structure on product distribution. Oxidations carried out at low tocopherol concentration gave only C-1 and C-5 conjugated diene hydroperoxides w...

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Detalhes bibliográficos
Main Authors: Tallman, Keri A., Rector, Christopher L., Porter, Ned A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2889150/
https://ncbi.nlm.nih.gov/pubmed/19331391
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900040d
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