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Fluctuations in Biological and Bioinspired Electron-Transfer Reactions

Central to theories of electron transfer (ET) is the idea that nuclear motion generates a transition state that enables electron flow to proceed, but nuclear motion also induces fluctuations in the donor-acceptor (DA) electronic coupling that is the rate-limiting parameter for nonadiabatic ET. The i...

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Détails bibliographiques
Auteurs principaux: Skourtis, Spiros S., Waldeck, David H., Beratan, David N.
Format: Artigo
Langue:Inglês
Publié: 2010
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2883780/
https://ncbi.nlm.nih.gov/pubmed/20192814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1146/annurev.physchem.012809.103436
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