Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94

The structures of two newly synthesized endohedral fullerenes - Tm@C(3v)-C(94) and Ca@C(3v)-C(94) - have been determined by single crystal X-ray diffraction on samples co-crystallized with Ni(II)(octaethylporphyrin). Both compounds exhibit the same cage geometry and conform to the isolated pentagon...

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Main Authors: Che, Yuliang, Yang, Hua, Wang, Zhimin, Jin, Hongxiao, Liu, Ziyang, Lu, Chunxin, Zuo, Tianming, Dorn, Harry C., Beavers, Christine M., Olmstead, Marilyn M., Balch, Alan L.
Format: Artigo
Language:Inglês
Published: 2009
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2878390/
https://ncbi.nlm.nih.gov/pubmed/19507844
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic900322d
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