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Formation of an Amine-Water Cyclic Pentamer: A New Type of Water Cluster in a Polyazacryptand
Structural analysis of an adduct of a thiophene-based cryptand with tosylic acid shows the formation of a hybrid amine-water cyclic pentamer composed of four water molecules and one protonated amine in the charged hydrophobic cavity. The bulky tosylate groups remain outside the cavity, making the li...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2873190/ https://ncbi.nlm.nih.gov/pubmed/20495666 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cg100161a |
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