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Mechanism of Shear Thickening in Reversibly Cross-linked Supramolecular Polymer Networks

We report here the nonlinear rheological properties of metallo-supramolecular networks formed by the reversible cross-linking of semi-dilute unentangled solutions of poly(4-vinylpyridine) (PVP) in dimethyl sulfoxide (DMSO). The reversible cross-linkers are bis-Pd(II) or bis-Pt(II) complexes that coo...

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Autori principali: Xu, Donghua, Hawk, Jennifer L., Loveless, David M., Jeon, Sung Lan, Craig, Stephen L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2869658/
https://ncbi.nlm.nih.gov/pubmed/20479956
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma100093b
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