Characterization of the Particulate Methane Monooxygenase Metal Centers in Multiple Redox States by X-ray Absorption Spectroscopy

The integral membrane enzyme particulate methane monooxygenase (pMMO) converts methane, the most inert hydrocarbon, to methanol under ambient conditions. The 2.8-Å resolution pMMO crystal structure revealed three metal sites: a mononuclear copper center, a dinuclear copper center, and a nonphysiolog...

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Autors principals: Lieberman, Raquel L., Kondapalli, Kalyan C., Shrestha, Deepak B., Hakemian, Amanda S., Smith, Stephen M., Telser, Joshua, Kuzelka, Jane, Gupta, Rajeev, Borovik, A. S., Lippard, Stephen J., Hoffman, Brian M., Rosenzweig, Amy C., Stemmler, Timothy L.
Format: Artigo
Idioma:Inglês
Publicat: 2006
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2864602/
https://ncbi.nlm.nih.gov/pubmed/16999437
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic060739v
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