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Probing ‘Spin-Forbidden’ Oxygen Atom Transfer: Gas-Phase Reactions of Chromium-Porphyrin Complexes

Oxygen-atom transfer reactions of metalloporphyrin species play an important role in biochemical and synthetic oxidation reactions. An emerging theme in this chemistry is that spin-state changes can play important roles, and a ‘two-state’ reactivity model has been extensively applied especially in i...

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Main Authors: Crestoni, Maria Elisa, Fornarini, Simonetta, Lanucara, Francesco, Warren, Jeffrey J., Mayer, James M.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2863096/
https://ncbi.nlm.nih.gov/pubmed/20218631
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9103638
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