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Hydrogen tunneling in adenosylcobalamin-dependent glutamate mutase: evidence from intrinsic kinetic isotope effects measured by intra-molecular competition
Hydrogen atom transfer reactions between substrate and coenzyme are a key mechanistic feature of all AdoCbl-dependent enzymes. For one of these enzymes, glutamate mutase, we have investigated whether hydrogen tunneling makes a significant contribution to the mechanism by examining the temperature-de...
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| Main Authors: | , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2010
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2851448/ https://ncbi.nlm.nih.gov/pubmed/20225826 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi1001695 |
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