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Dictazoles: Potential Vinyl Cyclobutane Biosynthetic Precursors to the Dictazolines

[Image: see text] We report here the isolation of five new compounds, dictazole A–B (1–2) and dictazoline C-E (5–7). Evidence is presented for the direct conversion of the cyclobutyl analogue 1 to its cyclohexyl constitutional isomer 5, via a vinyl cyclobutane rearrangement.

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Detalhes bibliográficos
Main Authors: Dai, Jingqiu, Jiménez, Jorge I., Kelly, Michelle, Williams, Philip G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2849972/
https://ncbi.nlm.nih.gov/pubmed/20222695
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902566n
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