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An Expedient Procedure for the Oxidative Cleavage of Olefinic Bonds with PhI(OAc)(2), NMO, and Catalytic OsO(4)
[Image: see text] PhI(OAc)(2) in the presence of OsO(4) (cat.) and 2,6-lutidine cleaves olefinic bonds to yield the corresponding carbonyl compounds, albeit, in some cases, with α-hydroxy ketones as by-products. A more practical and clean protocol to effect oxidative cleavage of olefinic bonds invol...
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| Main Authors: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2010
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2848477/ https://ncbi.nlm.nih.gov/pubmed/20192259 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100290a |
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