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Hexachloroethane: a highly efficient reagent for the synthesis of chlorosilanes from hydrosilanes

A new and efficient chlorination protocol is presented for the preparation of chlorosilanes from hydrosilanes. A variety of chlorinating agents in combination with palladium(II) chloride as the catalyst are examined. Among them, hexachloroethane is found to be the best choice, furnishing the desired...

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Detalhes bibliográficos
Main Authors: Pongkittiphan, Veerachai, Theodorakis, Emmanuel A., Chavasiri, Warinthorn
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2847782/
https://ncbi.nlm.nih.gov/pubmed/20360997
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.05.087
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