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Thermochemistry and Molecular Structure of a Remarkable Agostic Interaction in a Heterobifunctional Ruthenium-Boron Complex
A boron-pendant ruthenium species forms a unique agostic methyl bridge between the boron and ruthenium atoms in the presence of a ligating solvent, acetonitrile. NMR inversion-recovery experiments enable measurement of the activation and equilibrium thermochemistry for formation of the agostic bridg...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2846719/ https://ncbi.nlm.nih.gov/pubmed/20088526 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909858a |
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