An Enantioselective Synthesis of the ABD Tricycle for (−)-Phomactin A Featuring Rawal’s Asymmetric Diels-Alder Cycloaddition

An enantioselective synthesis of the ABD-ring of (−)-phomactin A is described here. The sequence features Rawal’s asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt.

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Bibliographic Details
Main Authors: You, Ling-Feng, Hsung, Richard P., Bedermann, Aaron A., Kurdyumov, Aleksey V., Tang, Yu, Buchanan, Grant S., Cole, Kevin P.
Format: Artigo
Language:Inglês
Published: 2008
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2846367/
https://ncbi.nlm.nih.gov/pubmed/20351791
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