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Enantioselective syntheses of candenatenins B and C using a chiral anthracene auxiliary
An asymmetric synthesis of two anticancer natural products, candenatenins B and C, is described, leading to a revision of the originally assigned stereochemistry. The synthesis follows a Diels-Alder/retro-Diels Alder strategy using a chiral anthracene auxiliary to access both targets with 90% ee. Th...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2010
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2839163/ https://ncbi.nlm.nih.gov/pubmed/20305722 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2009.12.108 |
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